Cycloaddition reactions represent a cornerstone of synthetic organic chemistry, facilitating the formation of cyclic structures through concerted pericyclic processes. Traditionally explained via ...

Azido complexes, which incorporate the linear azide ligand (N₃⁻), have emerged as versatile intermediates in the construction of diverse heterocyclic frameworks. The inherent reactivity of these ...

Cubene and quadricyclene are descended from cubane and quadricylane, both cage-shaped structures with bonds that are fairly ...

Researchers have engineered a novel M 6 L 4 octahedral molecular cage by integrating photoactive cyclometalated platinum(II) units, creating a visible-light-responsive "nanoreactor" that drives highly ...

Atomic precise [Au 13 Ag 12 (PPh 2 Py) 10 Cl 8]PF 6 supported on activated carbon (AC) achieves a TON of 3.03×10 4 as a catalyst for epoxide cycloaddition with CO 2. The catalyst shows potential ...

This module teaches fundamentals of pericyclic reactions using examples of biocatalysis, biomimetic catalysis, and natural product total synthesis. After completion, students should be able to ...